Ruthenium catalysts for olefin metathesis

Ring opening olefin metathesis

ACS Catalysis , 9 1 , Hughes, David R. Higman, Daniel L. Organometallics , 35 22 , The Schrock catalysts are more active and are useful in the conversion of sterically demanding substrates, while the Grubbs catalysts tolerate a wide variety of functional groups. Grubbs Reaction Olefin Metathesis allows the exchange of substituents between different olefins - a transalkylidenation. Christopher A. Journal of the American Chemical Society , 44 , Keister, and Steven T. Macromolecules , Cited By This article is cited by publications.

Organometallics37 8 Journal of the American Chemical Society2 Higman, Craig S. Grubbs' catalysts: evidence for one unique active species from two different systems!

intermolecular carbonyl olefin metathesis

Design of the boomerang ligand toward the optimal compromise between activity and reusability. Organometallics35 4 Houk, and Christopher D.

Allene metathesis

Washburn, Brad H. ACS Catalysis , 8 12 , The second generation Grubbs catalysts are even more stable and more active than the original versions. Liberman-Martin and Robert H. Stephanie A. Lam, Hung V. Received Sep 1; Accepted Nov DOI: In: Seidel A ed. Ring opening metathesis can employ an excess of a second alkene for example ethene , but can also be conducted as a homo- or co-polymerization reaction.

Hofman, Jerome B. Nowalk, Cheng Fang, Amy L.

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Recent Advances in Ruthenium Catalysts for Alkene Metathesis